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Abstract We present results from conducting a theoretical chemical analysis of a sample of benchmark companion brown dwarfs whose primary star is of type F, G, or K. We summarize the entire known sample of these types of companion systems, termed “compositional benchmarks,” that are present in the literature or recently published as key systems of study in order to best understand brown dwarf chemistry and condensate formation. Via mass balance and stoichiometric calculations, we predict a median brown dwarf atmospheric oxygen sink of by utilizing published stellar abundances in the local solar neighborhood. Additionally, we predict a silicate condensation sequence such that atmospheres with bulk Mg/Si ≲0.9 will form enstatite (MgSiO3) and quartz (SiO2) clouds, and atmospheres with bulk Mg/Si ≳0.9 will form enstatite and forsterite (Mg2SiO4) clouds. The implications of these results on C/O ratio trends in substellar-mass objects and the utility of these predictions in future modeling work are discussed.more » « less
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Calamari, Emily; Faherty, Jacqueline K.; Burningham, Ben; Gonzales, Eileen; Bardalez-Gagliuffi, Daniella; Vos, Johanna M.; Gemma, Marina; Whiteford, Niall; Gaarn, Josefine (, The Astrophysical Journal)Abstract We present results from an atmospheric retrieval analysis of Gl 229B using the Brewster retrieval code. We find the best fit model to be cloud-free, consistent with the T dwarf retrieval work of Line et al.; Zalesky et al. and Gonzales et al. Fundamental parameters (mass, radius, log(LBol/LSun), log(g)) determined from our model agree within 1σto SED-derived values, except forTeffwhere our retrievedTeffis approximately 100 K cooler than the evolutionary model-based SED value. We find a retrieved mass of MJup, however, we also find that the observables of Gl 229B can be explained by a cloud-free model with a prior on mass at the dynamical value, 70MJup. We are able to constrain abundances for H2O, CO, CH4, NH3, Na and K and find a supersolar C/O ratio as compared to its primary, Gl 229A. We report an overall subsolar metallicity due to atmospheric oxygen depletion, but find a solar [C/H], which matches that of the primary. We find that this work contributes to a growing trend in retrieval-based studies, particularly for brown dwarfs, toward supersolar C/O ratios and discuss the implications of this result on formation mechanisms and internal physical processes, as well as model biases.more » « less
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